- Thermodynamic properties relationships in most substance are complex
- calculation using the relations and measurable properties
- frequently presented in the form of tables e.g. steam table
The combination u + Pv is frequently encountered in the analysis of control volumes
Enthalpy of vaporization, hfg :- (Latent heat of vaporization)
The amount of energy needed to vaporize a unit
mass of saturated liquid at a given temperature
or pressure.
Quality x : The ratio of the mass of vapor to the total mass of the mixture.
- Temperature and pressure are dependent properties for a mixture.
Superheated Vapor ;-
Region to the right of the saturated vapor line, substance is in superheated vapor where temperature and pressure are independent properties.
3.6 The Ideal-gas Equation of State
- Equation of state: Relates pressure, temperature, and specific volume of substance.
- The simplest and best-known equation of state for substances in the gas phase is the ideal-gas equation of state.
- It can predict P-v-T with simpler calculation and accurately within some properly selected region (Real gases behave as an ideal gas at low P, high T)
Gas constants of different substances