1.1 Thermodynamics and Energy
Thermo dynamics
(Heat) (Power)
Thermodynamics is the study of the effects of work, heat and energy on a system.
Thermodynamics Laws >>>>>>
- 0th Law - Thermal equilibrium
- 1st Law - Conservation of energy,energy cannot be destroyed but can change forms
- 2nd Law - Energy has quantity and direction, entropy
1.2 Importance of Dimensions and Units
1.3 Systems and Control Volume
System
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Closed System
(Control mass)
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Open System
(Control volume)
|
Heat and
Work
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Heat and work (energy) crosses the
system when undergoing a process
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Heat and work (energy) crosses the
system when undergoing a process
|
Mass
Transfer
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Without any mass transfer when
undergoing a process
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With mass transfer when undergoing a
process
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Example
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Closed piston cylinder, bomb
calorimeter, pressure cooker
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Turbine, compressor, nozzle
|
1.4 Properties of a System
1.5 Density and Specific Gravity
- Intensive properties (Independent on mass) - Pressure P, Temperature T, Density ρ
- Extensive properties (Dependent on mass) - Mass m, Volume V
Density = mass per unit volume
Specific volume = volume per unit mass
v = V/m = 1/ρ
Specific gravity = density of substance / density of water
1.6 State and Equilibrium
- Thermal Equilibrium - temperature constant throughout the system
- Mechanical Equilibrium - constant pressure at any point of the system with time
- Phase Equilibrium - two phases where the mass of each phase reaches an equilibrium level and stays there
- Chemical Equilibrium - the chemical composition of a system dos not change with time
The State Postulate
- Simple compressible system is a system in the absence of external forces including electrical, magnetic, gravitational, motion and surface tension effects.
- State Postulate states that the state of a simple compressible system is specified by two independent intensive properties, which are temperature and pressure for single phase system.
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